The naphtha feed enters the unit through charge pump piol. The chemical composition of a gasoline blend consists of hydrocarbon chains. Sulfur and nitrogen compounds present in naphtha cut from atmospheric distillation column can deactivate the catalyst and must be removed prior to catalytic reforming. After the naphtha hydrotreating unit, naphtha is sent to an isomerisation unit or a catalytic reformer unit, which often use reforming catalysts. Petroleum naphtha naphtha is a complex mixture of liquid hydrocarbons, with boiling ranges of about 40 to 140 c and with vapor pressures of about 0. Dividing wall columns in naphtha hydrotreating nht units as shown in figure 2 and figure 3, the stabilizer can be replaced with a proprietary top dividing wall column. A read is counted each time someone views a publication summary such as the title, abstract, and list of authors, clicks on a figure, or views or downloads the fulltext. The nht unit prepares feedstock for downstream reforming or isomerization units that have sensitive noble metal catalyst. The fibers produced from nano zeolitey show superior performance with a total conversion of 98. Conventional naphtha hydrotreating and isomerization process scheme.
Though most refiners will process a blend of several crudes at any one time and a. Naphtha is hydrotreated for removal of metal and sulphur. It contains many different compounds such as paraffins, isoparaffins, olefins. Depending on which stream undergoes treatment, the hydrotreating unit can be.
Pdf revamp of naphtha hydrotreating process in an iranian refinery. Proper design and operation of a naphtha hydrotreater combined. The naphtha hydrotreating process is also important to pretreat naphtha for downstream units, like paraffin isomerization and catalytic reforming, where severe specifications are required and catalysts used are very sensitive to impurities. Hydrotreating of naphtha hds is one of the important units in crude oil refineries in whichcompounds such as sulfur, nitrogen, oxygen and metal are removed. Most reforming catalysts contain platinum as the active material. Improvement of the operation cycle time of a naphtha hydrotreating.
Crude distillation, catalytic cracking, delayed coking and visbreaking units produce naphtha with low octane number and contain deferent types of contaminants at the same time. Visbreaker gas oil blend stocks for diesel, fuel oil naphtha, middle distillates. The feedhydrogen mix is next heated in succession through heat exchange with reactor effluent in eiol and fired heater hiol. Naphtha hydrotreating reactor catalyst bed grading youtube. The heated feed hydrogen mix next enters the desulfurization reactor viol at the top. An equivalent naphtha is obtained as a product, requiring conventional refining. Design parameters for a hydro desulfurization hds unit. Sulphur, metal, polyaromatics and conradson carbon removal from vacuum gas oil vgo to be used as fcc feed. It is mixed with hydrogen gas coming from a cat reforming unit or hydrogen plant. A commonly used hdscatalyst is molybdenumnickel on alumina support.
Revamp of naphtha hydrotreating process in an iranian refinery. In hydrotreating units, reactions that convert organic sulfur and nitrogen. Network of dividing wall columns in complex process units. Purpose of the naphtha hydrotreating unit is to remove sulphur and nitrogen compounds. Feed to a distillate hydrotreating unit may be any blend or combination of straight run distillate. David krenzke, regional manager of hydrotreating technical services for. Pdf hydrotreating of naphtha hds is one of the important units in crude oil refineries in whichcompounds such as sulfur, nitrogen, oxygen. Nht naphtha hydrotreating unit is a functional to perform the decomposition components of sulfur, oxygen, nitrogen, and metal compounds. Naphtha hydrotreating is an essential step for refiners to produce cleaner gasoline from different feedstocks. Process work of a naphtha hydrotreating unit proses industri.
1216 338 636 95 627 1260 141 1092 1072 293 687 247 356 835 259 163 1570 734 255 1140 615 287 1122 729 561 1447 735 724 850 467 944 353 984 1460 977 11 76 91 554 634 1380 1227